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Aromatic-radical oxidation kinetics

Aromatic-radical oxidation kinetics

Abstract

Research progress in three areas is described. Progress achieved in the extensive experimental investigation of the oxidation and pyrolysis of cyclopentadiene is summarized first. The mechanistic implications of the experimental work are also discussed. An overview is given of the successful research effort devoted to modelling flow reactor toluene and benzene oxidation data. As mentioned above, one of the ultimate goals of this research is to develop a comprehensive, detailed chemical kinetic model of aromatics oxidation. The success already achieved in this effort augurs well for reaching the broader goal. The toluene/benzene model, however, does have a number of shortcomings which suggest the need for further experiments. A description is given of attempts to predict the laminar flame speeds of toluene and benzene. The difficulties encountered and the solutions found highlight the need of an examination of certain chemical steps that impact most the energy release of a burning aromatic fuel.

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United States
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Keywords

& High-Temperature Chemistry, Carbon Oxides, Chemical Reaction Kinetics, Polyenes, Alkenes, Thermochemical Processes 400800* -- Combustion, Laminar Flow, 37 Inorganic, Oxidation, Reaction Kinetics, Chemical Reactors, Cycloalkenes, Dienes, Fluid Flow, Carbon Monoxide, Decomposition, Organic, Progress Report, Flames, Organic Compounds, Mathematical Models, Chemical Reactions, Oxides, Alkylated Aromatics, Benzene, Carbon Dioxide, Document Types, Carbon Compounds, Hydrocarbons, Combustion Kinetics, Kinetics, Sensitivity Analysis, Aromatics, Physical And Analytical Chemistry, Oxygen Compounds, Concentration Ratio, Pyrolysis, Cyclopentadiene, Toluene, Chalcogenides

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
2
Average
Average
Average