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Residence time distribution

Residence time distribution

Abstract

Slurry phase residence time in the SRC-II dissolver is a major process variable affecting the extent of conversion to distillate products. Kinetic studies have shown that overall conversion of vacuum bottoms to lighter hydrocarbons is a zero order process with respect to vacuum bottoms. This implies that although the extent of backmixing is not a critical process variable, slurry phase mean residence time is. Experimental results from the P-99 PDU supported this. Radioactive tracers were injected into the Ft. Lewis dissolver during normal operation to study the residence time distribution of the gas and slurry phases. Results from gas phase radiotracers showed the gas phase to approach plug flow behavior, but with much larger than expected gas holdup. Gas holdup appeared to be 20% of the reactor volume, rather than the 10 to 12% predicted by standard holdup correlations. Slurry phase radiotracer results indicated that the slurry phase was well-backmixed. Experiments with a downcomer designed to enhance direct slurry flow from the top to the bottom of the dissolver showed this to be a viable and controllable device. The high level of gas holdup at Ft. Lewis suggest that standard holdup correlations must be modified to be used with confidence in the design of coal liquefaction reactors. Additional programs to define holdup relationships in high temperature, high pressure coal liquefaction reactors are recommended. 11 references, 6 figures, 6 tables.

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Keywords

& Peat-- Hydrogenation & Liquefaction, And Peat, Design, Src-Ii Process, Process Development Units, Multiphase Flow, Coal Liquefaction, Functional Models, Industrial Plants, Mixing, Information, Lignite, Chemical Reactors, Time Dependence, Fluid Flow, Data, Correlations, Thermochemical Processes 010405* -- Coal, Pilot Plants, Labelled Compounds, 01 Coal, Liquefaction, Numerical Data, Experimental Data, Isotope Applications, Coal Liquefaction Plants, Tracer Techniques

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average