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Gelcasting of silicon compositions for SRBSN

Authors: Nunn, S.D.; Kiggans, J.O. Jr.; Simpson, R.E. II; Maria, J.P.;

Gelcasting of silicon compositions for SRBSN

Abstract

Compositions of high purity silicon metal containing various oxides as sintering aids were gelcast to prepare green bodies for subsequent nitridation and sintering to form sintered reaction bonded silicon nitride (SRBSN). An acidic aqueous and an alcohol-based gelcasting system were used. The solids content in the slurry affected the green density of the cast samples, however, there was no apparent correlation between the green density and the percent nitridation. Samples were nitrided under flowing, high-purity nitrogen in either a tungsten element furnace, a graphite element furnace, or in a microwave furnace. The samples nitrided in the graphite and microwave furnaces showed 9--16% higher levels of nitridation than in the tungsten furnace. A N{sub 2}-4% H{sup 2} gas mixture was compared to pure nitrogen in the tungsten furnace. The addition of the hydrogen increased nitridation levels by 14--19%. The nitrided and sintered SRBSN ceramics had densities of 95--98% of theoretical, with no direct relationship being observed between the level of nitridation and the fired density. The average 4-point flexure strength of the samples ranged from 428 to 741 MPa.

Country
United States
Related Organizations
Keywords

Sintering, Nitridation, 36 Materials Science, Silicon Nitrides, Binders, Mechanical Properties, Experimental Data, Fracture Properties, Casting

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
1
Average
Average
Average