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Evaporation of J13 water: laboratory experiments and geochemical modeling

Authors: Dibley, M.J.; Knauss, K.G.; Rosenberg, N.D.;

Evaporation of J13 water: laboratory experiments and geochemical modeling

Abstract

We report results from experiments on the evaporative chemical evolution of synthetic J13 water, representative of water from well J13, a common reference water in the Yucca Mountain Project. Data include anion and cation analysis and qualitative mineral identification for a series of open system experiments, with and without crushed tuff present, conducted at sub-boiling temperatures. Ca and Mg precipitated readily as carbonates and anions Cl, F, NO{sub 3} and SO{sub 4} remained in solution in nearly identical ratios. The pH stabilized at about 10. After {approx} 1000x concentration, the minerals formed were amorphous silica, aragonite and calcite. The presence of tuff appears to have very little effect on the relative distribution of the anions in solution, except for possibly F, which had a relatively lower concentration ratio. The Si was lower in the solutions with tuff present suggesting that the tuff enhances SiO{sub 2} precipitation. Even though the tools to model highly-concentrated salt solutions are limited, we compare our experimental results with the results of geochemical models, with (perhaps) surprising good results. In response to different assumed CO{sub 2} levels, pH varied, but anion concentrations were not greatly affected.

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United States
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Keywords

And Non-Radioactive Wastes From Nuclear Facilities, Evaporation, Calcite, Carbonates, 12 Management Of Radioactive Wastes, Silica, 11 Nuclear Fuel Cycle And Fuel Materials, Aragonite, Geochemistry, Tuff, Ground Water, Concentration Ratio, Radioactive Waste Facilities, Yucca Mountain

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
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