
doi: 10.2172/10192749
A novel, growing-drop technique is described for measuring dynamic interfacial tension due to sorption of surface-active solutes. The proposed method relates the instantaneous pressure and size of expanding liquid drops to interfacial tension and is useful for measuring both liquid/gas and liquid/liquid tensions over a wide range of time scales, currently from 10 ms to several hours. Growing-drop measurements on surfactant-free water/air and water/octanol interfaces yield constant tensions equal to their known literature values. For surfactant-laden, liquid drops, the growing-drop technique captures the actual transient tension evolution of a single interface, rather than interval times as with the classic maximum-drop-pressure and drop.-volume tension measurements. Dynamic tensions measured for 0.25 mM aqueous 1-decanol solution/air and 0.02 kg/m{sup 3} aqueous Triton X-100 solution/dodecane interfaces show nonmonotonic behavior, indicating slow surfactant transport relative to the imposed rates of interfacial dilatation. The dynamic tension of a purified and fresh 6 mM aqueous sodium dodecyl sulfate (SDS) solution/air interface shows only a monotonic decrease, indicating rapid surfactant transport relative to the imposed rates of dilatation. ConverselY, an aged SDS solution, naturally containing trace dodecanol impurities, exhibits dynamic tensions which reflect a superposition of the rapidly equilibrating SDS and the slowly adsorbing dodecanol.
Experimental Data 020300, Decanols, Organic, Chemical And Physicochemical Properties, Air, Surfactants, 02 Petroleum, Interfaces, 400201, Drilling And Production, Measuring Methods, Aqueous Solutions, 540, 530, 37 Inorganic, Physical And Analytical Chemistry, Surface Tension, Dodecane, Droplets
Experimental Data 020300, Decanols, Organic, Chemical And Physicochemical Properties, Air, Surfactants, 02 Petroleum, Interfaces, 400201, Drilling And Production, Measuring Methods, Aqueous Solutions, 540, 530, 37 Inorganic, Physical And Analytical Chemistry, Surface Tension, Dodecane, Droplets
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