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Spatially confining and electronically reconnecting dead lithium in a hierarchical host for long-life lithium metal batteries

Authors: Hongyan Li; Zhiwei He; Hongxian Zhang; Tengfei Xu; Ouwei Sheng; Qingyue Han; Gongxun Lu; +3 Authors

Spatially confining and electronically reconnecting dead lithium in a hierarchical host for long-life lithium metal batteries

Abstract

The prolonged operation of high-energy-density lithium (Li) metal batteries (LMBs) hinges on reactivating irreversible Li (i.e., dead Li comprises isolated-Li0 debris and residual SEI), not just preventing its formation. However, concurrently achieving dead-Li suppression and rejuvenation remains challenging. Here, we design an N-doped hierarchically porous carbon (NHPC) host that enables bottom-up, uniform Li deposition via its interconnected ordered porosity and lithiophilic N-dopant sites, reducing dead Li formation. Notably, the lifespans of LiFePO4 cells using NHPC hosted Li is increased by 3 times, where limited dead Li that is dominated by isolated Li0 (a more reactivatable dead Li source) accumulates in NHPC. The porous structure of NHPC induces thin solid-electrolyte interphase, spatially confines dead Li and provides abundant electronic conducting pathways. These features collectively promote the electronic reconnection of isolated Li0 with the electrode by applying a facile resting protocol, recovering 28.3% Li loss and further extending the lifespan of NHPC@Cu||LiFePO4 cells by another ~100%. The feasibility of NHPC host can further be translated into low-temperature and pouch cells that suffer worse dead-Li issues. This work offers a new design perspective for functional hosts to revive dead Li and advance long-life Li metal batteries.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
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