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Challenges in the Reliable Detection of Lithium Plating using Dynamic Electrochemical Impedance Spectroscopy

Authors: Raphael Urban; Mathieu Seyfritz-Comby; Christian Peter; Kareem Abo Gamra; Cristina Grosu; Markus Lienkamp;

Challenges in the Reliable Detection of Lithium Plating using Dynamic Electrochemical Impedance Spectroscopy

Abstract

Fast charging of lithium-ion batteries is strongly limited by the risk of lithium plating, which accelerates aging and compromises safety. While electrochemical impedance spectroscopy has been widely explored for plating detection, significant challenges regarding its practical reliability and signal interpretation remain insufficiently addressed. Three commercially available 18650 lithium-ion cell types representing both high-energy and high-power designs are examined. Therefore, an experimental setup with single-sine and multi-sine excitation was developed to analyze the dynamic impedance under different excitation signals, C-rates, and temperatures. The evolution of impedance is evaluated in conjunction with voltage relaxation behavior to identify characteristic features associated with lithium plating. Higher-order derivatives of the impedance are assessed as potential mathematical metrics for plating detection. However, a sensitivity analysis reveals that the accuracy of the metrics depends on signal quality and post-processing parameters, leading to shifts in the suspected plating onset or the introduction of artifacts. Consequently, robust signal post-processing is essential to ensure the reliability and accuracy of impedance-based plating detection.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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Average
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