Powered by OpenAIRE graph
Found an issue? Give us feedback
image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ HAL-CEAarrow_drop_down
image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
HAL-CEA
Article . 2025
License: CC BY
Data sources: HAL-CEA
image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
HAL-INSU
Article . 2025
License: CC BY
Data sources: HAL-INSU
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Journal of Nuclear Materials
Article . 2025 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
https://doi.org/10.2139/ssrn.5...
Article . 2025 . Peer-reviewed
Data sources: Crossref
versions View all 4 versions
addClaim

Low Pressure Glass-Ceramics for the Immobilization of Long-Lived Iodine Radioisotopes

Authors: Yann Morizet; Gabin Haryouli; Sami Soudani; Hanyu Hu; Michael Paris; Philippe Deniard; Lionel Campayo; +1 Authors

Low Pressure Glass-Ceramics for the Immobilization of Long-Lived Iodine Radioisotopes

Abstract

There have been substantial scientific works in the past years for finding adequate immobilization matrices for iodine radioisotopes. Lately, iodosodalite glass-ceramics or glasscomposites represent a promising material. Under pressure, glass-ceramics represent an even better material. In the present work, we have synthesised I-bearing glass-ceramics under low pressure conditions (0.5 GPa) and using a thermal step from melting (1250°C) to crystallization temperature (813°C). The produced materials show the coexistence between Irich iodosodalite (>10 mol.% I) and I-poor glass matrix (<1 mol.% I) and without the presence of detrimental crystalline phase such as nepheline. The iodosodalite proportion remains low though (~10%). Raman spectroscopy on the iodosodalite crystals seems to indicate that the β cage could be filled either with I$^-$ or IO3$^-$ species. The analyses of the glass structure using 11B NMR show an increase in the BO4 proportion that could suggest an increase in the chemical durability. In the end, the produced materials have most of the prerequisite for a relevant matrix for immobilization of iodine radioisotopes.

Country
France
Keywords

[CHIM.MATE] Chemical Sciences/Material chemistry, [CHIM.RADIO] Chemical Sciences/Radiochemistry, chemical durability, Low-pressure glass-ceramics, iodine radioisotopes immobilisation

  • BIP!
    Impact byBIP!
    selected citations
    These citations are derived from selected sources.
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    1
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Average
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Average
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Average
Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
1
Average
Average
Average
Green