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Carbohydrate Research
Article . 2023 . Peer-reviewed
License: CC BY
Data sources: Crossref
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https://doi.org/10.2139/ssrn.4...
Article . 2023 . Peer-reviewed
Data sources: Crossref
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Identification of the Furanose Ring Conformations and the Factors Driving Their Adoption

Authors: Dominik Walczak; Artur Sikorski; Daria Grzywacz; Andrzej Nowacki; Beata Liberek;

Identification of the Furanose Ring Conformations and the Factors Driving Their Adoption

Abstract

Three groups of furanoses with restricted freedom of rotation on the C3-C4, C2-C3, and C1-C2 bonds, respectively, are presented. Conformational analysis of these furanoses is conducted based on the proton nuclear magnetic resonance (1H NMR) spectroscopy, density functional theory (DFT) calculations, and X-ray analysis. It is shown that the particular group of the presented furanoses is locked in the specific conformation. These are the 1T2-like, the 0E-like, and the 3T4-like conformation, respectively. Characteristic 1H NMR spectra of these three conformations are presented and the factors influencing the conformational preferences of the analyzed furanoses are discussed.

Country
Poland
Related Organizations
Keywords

anomeric effect, 3-pseudodiaxial interactions, Models, Molecular, Magnetic Resonance Spectroscopy, twist conformation, efekt anomeryczny, 1, konformacja twistowa, Molecular Conformation, orientacja ekliptyczna, ecliptic orientation, zerowa stała sprzężenia, 3-pseudodiaksjalne oddziaływania, envelope conformation, konformacja kopertowa, zero coupling constant

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
11
Top 10%
Average
Top 10%
hybrid