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Ice-Templated Porous Tungsten and Tungsten Carbide

Authors: Yuan Zhang; Guoqi Tan; Da Jiao; Jian Zhang; Shaogang Wang; Feng Liu; Zengqian Liu; +4 Authors

Ice-Templated Porous Tungsten and Tungsten Carbide

Abstract

The structures of tungsten and tungsten carbide scaffolds play a key role in determining the properties of their infiltrated composites for multifunctional applications. However, the architectural construction of W/WC systems is challenging because of the difficulty of assembly due to their large densities. Here we present the generation of unidirectionally porous architectures, with high porosities exceeding 65%, for W and WC scaffolds using direct ice-templating techniques, which in many respects reproduce the design motif of wood. This was achieved by adjusting the viscosities of suspensions to retard sedimentation during freezing. The processing, structural characteristics and mechanical properties of the resulting scaffolds were investigated and the correlations between them explored. Quantitative relationships were established to describe their strengths based on a simple model taking into account both inter- and intra-lamellar pores. The fracture mechanisms were also identified, especially in light of the porosity. This study extends the effectiveness of ice-templating techniques for systems with large densities or particle sizes. It further provides preforms for developing new nature-inspired multifunctional materials, as represented by W/WC-Cu composites.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
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