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Basalts as Probes of Planetary Interior Redox State

Authors: C. D. K. Herd;

Basalts as Probes of Planetary Interior Redox State

Abstract

Whether the redox state, quantified as oxygen fugacity, recorded in a planetary basalt is an accurate representation of the redox state of the planetary interior from which it was derived through partial melting, ascent, eruption and emplacement is a fundamental question in planetary geology. In the absence of mantle xenoliths in samples from the Moon, Mars and differentiated asteroids, the basalt-mantle source relationship must be extrapolated from what is known about the Earth in order to probe the redox state of these planetary interiors. A review of current knowledge regarding the basalt-mantle source relationship for the Earth provides insights into the advantages and pitfalls of determining mantle redox state. The range of currently available oxybarometers, including thermodynamic models based on ferrous-ferric mineral equilibria and multivalent cation analysis are surveyed and their limitations presented. The result is a basis for the informed interpretation of the oxygen fugacity of planetary basalts, and new insights into the role of C-H-O volatiles in the terrestrial planets.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
69
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Top 10%
Top 10%
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