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Synthesis and characterization of saponite clays

Authors: Vogels, R. J.M.J.; Kloprogge, J. T.; Geus, J. W.;

Synthesis and characterization of saponite clays

Abstract

A new procedure has been developed for a fast preparation of saponite clays under the non-hydrothermal synthesis conditions of 90 degrees Celsius and 1 atmosphere. Saponites were synthesised from a stoichiometric mixture containing Si/Al3+ gel, M2+-nitrate (M2+ = Mg, Zn, Ni, Co, or Cu), urea and water within a few hours. The synthesis products were characterised with XRD, IR, TEM, XRF, N2-physisorption, Al-EXAFS, and 27Al- and 29Si-MASNMR Incorporation of Mg, Zn, Co, Ni, or a combination of these cations in the octahedral sheet, as well as controlling the Si/Al ratio in the tetrahedral sheet in the range between 5.67 and 39.0 could easily be established. Pure Cu-saponite could not be synthesised due to the preferred formation of chrysocolla, but a combination of Mg2+ and Cu2+ resulted in saponite formation. The chemical composition strongly influences the textural properties of the saponites. It is possible to prepare saponite samples of a specific surface area and pore volume of 100 to 750 m2/g and 0.15 to 1.05 ml/g, respectively. The lateral size and the amount of stacking of the saponite platelets could be influenced by the composition, synthesis duration and amount of urea. The new synthesis procedure provides an easy way to prepare high quantities of saponites with far-reaching control on the texture as well as the composition.

Country
Australia
Keywords

Synthesis, Soponite, XRD, 1906 Geochemistry and Petrology, TEM, 1908 Geophysics, 540

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
65
Top 10%
Top 10%
Average
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