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Mechanisms and Processes for Conversion of Smaller Boranes to Larger Boranes or Borane Fragments.

descriptionPublicationkeyboard_double_arrow_right Report , Other literature type 01 Oct 1980Publisher:Defense Technical Information Center
Authors: Goji Kodama; Robert W. Parry;

doi: 10.21236/ada093783

Mechanisms and Processes for Conversion of Smaller Boranes to Larger Boranes or Borane Fragments.

Abstract

Abstract : Successful isolation and characterization of Me3NB4H8 revealed an aspect of the base catalysis of borane condensation, and triggered the discovery of new hypho class compounds B4H8(2PMe3) and B3H5(3PMe3). Formation of a new class (klado) of compound B4H6(4PMe3) was confirmed also. These higher class compounds are promising reagents for borane expansion. A triborane cation, (B3H6(PMe3)2)+, was prepared from B2H4(2PMe3). The diborane(4) adduct can be used as a reagent for borane expansion. An attempted conversion of B5H9 to B10H14 is described. (Author)

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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