The meteorological optical range (MOR) is an objective parameter for assessing atmospheric visibility. Data collected using optical disdrometers (PWS100) were used to analyze MOR estimates when extreme rainfalls occurred at two locations in Mexico: Chamela, on the Pacific coast, and Juriquilla, a continental sampling site. The performance of the disdrometer for rainfall estimation was found to be consistent and satisfactory when compared to rain gauges. Analyses based on rainfall rate (R) outcomes from tipping bucket rain gauge data showed that MOR measurements registered the most significant decreases during periods of highest R. The assessed coefficients for the extinction coefficient (σ) and R power-adjusted relationships are comparable to those obtained in previous studies, and the statistical performance of the fitted equations in modeling σ values is excellent. The equation coefficients for these mathematical expressions indicate that precipitation at the sampling sites is initiated from mixed (Bergeron-type) clouds, and it can be inferred that mixed-phase thunderstorms were predominant at the sampling sites during the chosen periods. Our findings indicate that MOR and σ are closely related to the large raindrop proliferation and the broadening of the raindrop size distribution (inferred from the increase of the median volume diameter). Despite the underestimation of small raindrops by the optical disdrometer, this study demonstrates the reliability of MOR estimates obtained with the PWS100 during rainfall events.