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Eurasian Chemico-Technological Journal
Article . 2013 . Peer-reviewed
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Eurasian Chemico-Technological Journal
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Fabrication of Fully Dense UHTC by Combining SHS and SPS

Authors: MUSA, CLARA; LICHERI, ROBERTA; ORRU', ROBERTO; CAO, GIACOMO;

Fabrication of Fully Dense UHTC by Combining SHS and SPS

Abstract

The combination of the Self-propagating High-temperature Synthesis (SHS) technique and the Spark Plasma Sintering (SPS) technology is adopted in this work for the fabrication of fully dense MB2-SiC and MB2-MC-SiC (M = Zr, Hf, Ta) Ultra High Temperature Ceramics (UHTCs). Specifically, Zr, Hf or Ta, B4C, Si, and graphite reactants are first converted to the desired composites by SHS. For the case of the low-exothermic Ta-based compositions, a preliminary 20 min ball milling treatment of the starting reactants is required to activate the corresponding synthesis reactions. When the resulting powders are then subjected to consolidation by SPS, it is found that products with relative densities greater than 96% can be obtained for all systems investigated within 30 min of total processing time, when setting the dwell temperature to 1800 °C and the mechanical pressure to 20 MPa. Hardness, fracture toughness, and oxidation resistance characteristics of the resulting dense UHTCs are comparable to, or superior than, those relative to similar products synthesized by alternative, less rapid, processing routes. Moreover, it is found that the ternary composites display relatively low resistance to oxidation as a consequence of the lower SiC content in the composite, in comparison with the binary systems, as well as to the presence of transition metal carbides. Indeed, although the latter ones are potentially able to increase mechanical and resistance to ablation properties, they tend to oxidize rapidly to form MO2 and COx, so that the resulting porosity make the material bulk more sensitive to oxidation.

Country
Italy
Keywords

Chemistry, QD1-999

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selected citations
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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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