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Article . 2017 . Peer-reviewed
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Porous structure of nano-dimensional boraso-graphenic powders

in English
Authors: Petrova, A.V.; Garbuz, V. V.; Lobunets, T.F.; Tomila, T.V.;

Porous structure of nano-dimensional boraso-graphenic powders

Abstract

?????????????????????? ?????????????????????? ?????????????????????? ???????????????? ???????????????????????????? ?????????????????????????? (t-BNg.). ???????????????????? ????????????????, ?????? ?? ???????????????? ?????????????? ?????????????? t-BNg ???????????????????? ??????????-, ???????????????????????? (????????????????????????????) ?? ?????????? ???????????????????????????? ???????????????? ?? ?????????????????? 3,82 - 4,12 ????, ?????? ?????????? ???????????????? ???????????????????? ?????????? ?? ?????????? 60% ?????????????????????? ??????????????. ?????????????? ?????????????? ?????????????????????? ???????????????? t-BNg ~ 30 ???? / ?? (t-??????????), ???????????????????? ?????????????? ~ 140 ???? / ?? (?????????? BJH). ???????????????????????????? ?????????????????????? ?????????? ?????????????????? ???????? ???? ???????????? ?????? ???????????????? ??????????. ?????????????? ?????????????????????? ???????? ?? ???????? ???????????????????? ??????????????????, ?????????????? ???????????? ??????????, ???????? ???????????????????????????? ???? ?????????????????? ?? ?????????????????????? ?????????????? t-BNg ?????? ?????????????????????? 540 ?? ?? ???????????????? ??? 1,0 ????. ????????????????, ???????????????? ???????????? ?????????????????????? ?????????????? ?? ???????????????????????? ??????????????????????????, ?????????????????????????????? ?? ?????????????????????????? ???????????????????????? ???????????? ????-??????????-????-????????-????????-????-??????-??????-?????????? ?????????????? H(OH)[(BON)???](OH)H. ???????????????????? ???????????? ???????????????????????? ?????????????? ?????????????? ????????, ?????? ???????????????????????????????????? ???????????????????? ?????????????????????? ??????????-?????????????????????? ?????????????????????? ?? ???????????????? ?????????????????????? ????????????-???????? (> ?? - N <).

???????????????????? ???????????????????? ?????????????????????? ???????????????? ???????????????????????????? ?????????????????????????? (t-BNg.). ???????????????????? ????????????????, ???? ?? ?????????????? ?????????????? ?????????????? t-BNg ???????? ??????????-, ????????-???????????????? (????????????????????????????) ?? ?????????????? ???????????????????? ???????????????? ?? ?????????????????? 3,82 ??? 4,12 ????, ???? ???????????? ???????????????? ?????????????????? ????'???? ?? ?????????????? 60% ???????????????? ??????????????. ?????????? ???????????????????? ???????????????? ???????????????? t-BNg ~ 30 ???? / ?? (t-??????????), ?????????????????????? ?????????????? ~ 140 ???? / ?? (?????????? BJH). ???????????????????????????? ???????????????? ?????????? ?????????????????? ???????? ???? ?????????????? ?????? ???????????????? ????????????. ?????????????? ???????? ?????????????????????? ?? ?????????????? ?????????????????? ??????????????????, ?????????????? ???????????? ??????????????, ???????? ???????????????????????? ?? ?????????????????? ???? ???????????????????? ???????????? t-BNg ?????? ?????????????????????? 540 ?? ?? ?????????? ??? 1,0 ????. ????????????????, ???????????? ?? ???????????? ?????????????????? ?????????????? ???? ?????????????????????????? ??????????????c??????????, ?????????????????????????????? ?? ???????????????????? ???????????????????? ???????????? ??????????????-????????????????????-???? ?????????????????????? ???????????? H(OH)[(BON)???](OH)H. ?????????????????????????? ???????????? ???????????????????????? ?????????????? ?????????????? ????????, ???? ?????????????????????????? ???????????????? ?????????????????????? ????????????-?????????????????????? ?????????????????????? ?? ???????????? ???????????????????? ????????????-???????? (> ?? ??? N <).

The structural features of surface of the nano-dimensional bor-azo-graphenic powders (t-BNg) after previous washing in boiling water were researched. The results showed that after process of purifier (washing) the powder???s surface of t-BNg characterized as slit-like micro-, mesoporous (monodispersed) structure with a narrow porous distribution in the range of 3.82 - 4.17 nm. The outer surface specific area of the powders of t-BNg according to ???t - method??? is 28.3 m??/g. The inner specific surface area of the mesopores is 141 m??/g (BJH method). The residues of boron oxonitride in the form of a purified sublimate, a white powder, extracted from a washed and dried sample of t-BNg at a temperature of 540 K and a pressure of ??? 1.0 Pa. The sublimate, according to chemical analysis and infrared spectroscopy, was identified on the assumption of the cyclic dimer of di-hydro-di-hydroxo-di-bor-ox-azole of the composition of H(OH)[(BON)???](OH)H. The model of carbamide synthesis of boron nitride, as a sequence of chemical transformations of borate-carbamide precursors in a freely radical boron-pair (> B - N <), have proposed.

Keywords

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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Average
Average
Average
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