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Intramolecular Force Field of Some Tetrahedral Thio and Seleno Anions

descriptionPublicationkeyboard_double_arrow_right Article 01 May 1974Publisher:Walter de Gruyter GmbHJournal:Zeitschrift für Naturforschung A, volume 29, pages 826-828 (issn: 0932-0784, eissn: 1865-7109,

Authors: Parvez Ahmad; Nitish K. Sanyal;

doi: 10.1515/zna-1974-0527

Intramolecular Force Field of Some Tetrahedral Thio and Seleno Anions

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Abstract

Abstract The orbital valence force field (OVFF) and the Urey- Bradley force field (UBFF) have been employed to evaluate the force constants of thio and seleno anions of VA, VB, VIB and VIIB group atoms of the periodic table. These constants were utilized to examine the relative strength of chemical bonds in isoelectronic sequences. Further, for these anions, the variation of the ratio L12/L21 with the mass coupling term (T = G12 √|G|) has been studied. This appears to be an excellent support to the extended L-matrix approximation **.

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Deen Dayal Upadhyay Gorakhpur University
India

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