
Radio-frequency reactively-sputtered films of c-oriented polycrystalline zinc oxide exhibit optical dispersion which differs significantly from published data on single crystal material. A model is developed which satisfactorily describes the bulk material, including birefringence and temperature dependence of dispersion, based on empirical absorption data and a theoretical band model. When the calculated equivalent oscillator strengths and energies are transferred to computations for the polycrystalline film it is found that the observed slight shift in absorption edge and a typical 95% packing density account for the data. Reaktiv hochfrequent aufgespruhte Schichten von c-orientiertem, polykristallinem Zinkoxid zeigen optische Dispersion, die sich betrachtlich von publizierten Werten an einkristallinem Material unterscheidet. Ein Modell wird entwickelt, das das Volumenmaterial befriedigend beschreibt, einschlieslich Doppelbrechung und Temperaturabhangigkeit der Dispersion, und auf empirischen Absorptionswerten sowie einem theoretischen Bandermodell beruht. Wenn die berechneten aquivalenten Oszillatorstarken und -energien auf die Rechnungen fur polykristalline Schichten ubertragen werden, wird gefunden, das die beobachtete leichte Verschiebung der Absorptionskante und eine typische 95%-Packungsdichte diese Werte erklart.
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