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UQ eSpace
Conference object . 2007
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Preparation and Characterization of Carbon Nitride Nanocage

Authors: Vinu, Ajayan; Mori, Toshiyuki; Ariga, Katsuhiko;

Preparation and Characterization of Carbon Nitride Nanocage

Abstract

A novel highly ordered three dimensional cage type mesoporous carbon nitride material (MCN-2 - CN nanocage) with very high surface area and pore volume has been prepared for the first time using three dimensional cage type mesoporous silica, SBA-16 as a template through a simple polymerization reaction between ethylenediamine and carbon tetrachloride. The material has been unambiguously characterized by various sophisticated techniques such as XRD, nitrogen adsorption, HRTEM, EELS, XPS, 13C DD-MAS, and FT-IR spectroscopy. The XRD result reveals that MCN-2 possesses three dimensional structure with a Im3m space group. The specific surface area and pore volume of MCN-2 are significantly higher as compared to those of the template and MCN-1. Because of the excellent textural characteristic and cage type three dimensional porous structure, we believe that the MCN-2 could offer great potential for the applications, such as catalytic supports, gas storage, lubricants, biomolecule adsorption and drug delivery.

Keywords

Nanocage, Mesoporous Silica, Carbon nitride, Molecular-Sieve, Mesoporous silica

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
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