We report on the observation of a modulated pattern induced by a single laser beam in a polymeric film. In spite of the simple geometrical configuration, the analysis of the far field diffraction pattern allows a sensitive retrieving of the wavelength of the recording beam and of its incidence angle, pointing out the high information content of the recorded spot. A theoretical model is presented which satisfactorily explains the observed behavior. It takes into account the interaction of structured light with structured matter with the same symmetries and spatial modulation frequencies close to each other. This result shows a feature of the interaction between structured light and structured matter which has not been explored yet.