Powered by OpenAIRE graph
Found an issue? Give us feedback
image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Polymer Journalarrow_drop_down
image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
Polymer Journal
Article
Data sources: UnpayWall
Polymer Journal
Article . 2000 . Peer-reviewed
Data sources: Crossref
versions View all 2 versions
addClaim

Electrostatic Contributions to Chain Stiffness and Excluded-Volume Effects in Sodium Poly(styrenesulfonate) Solutions

Authors: IWAMOTO, Yoshimi; HIROSE, Eigo; NORISUYE, Takashi;

Electrostatic Contributions to Chain Stiffness and Excluded-Volume Effects in Sodium Poly(styrenesulfonate) Solutions

Abstract

Intrinsic viscosities for sodium poly(styrenesulfonate) in aqueous sodium chloride at 25°C have been determined for 15 samples ranging in weight-average molecular weight from 3.8×103 to 6.5×105 at five salt concentrations Cs between 0.05 and 2M. Their molecular weight dependence at each Cs is fairly satisfactorily explained by the theory of Yoshizaki et al. for unperturbed wormlike chains combined with the quasi-two-parameter theory for excluded-volume effects. The estimated persistence length q and excluded-volume strength B both increase with decreasing Cs. This increase in q is not quantitatively described by the known theories for the electrostatic persistence length when the previously determined q of 0.69nm in 4.17M aqueous NaCl at the theta point is used for the intrinsic persistence length. It is. also shown that the values of B computed on the conventional bead model and the rodlike segment model in the Debye—Hueckel approximation with the ion condensation hypothesis are too large compared to the experimental estimates at lower Cs of 0.05 and 0.1M though the latter model gives considerably smaller B than does the former one.

Related Organizations
Keywords

Poly(styrenesulfonate), Chain Stiffness, Electrostatic Persistence Length, Excluded-Volume Effect, Polyelectrolyte, Wormlike Chain

  • BIP!
    Impact byBIP!
    selected citations
    These citations are derived from selected sources.
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    26
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Average
Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
26
Top 10%
Top 10%
Average
bronze