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Polymer Journal
Article
Data sources: UnpayWall
Polymer Journal
Article . 1979 . Peer-reviewed
Data sources: Crossref
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Crystallization Kinetics of Fractionated Polyethylenes at High Pressures by a DTA Method

Authors: Shuichi Sawada; Takuhei Nose;

Crystallization Kinetics of Fractionated Polyethylenes at High Pressures by a DTA Method

Abstract

The crystallization kinetics of fractionated polyethylenes under high pressure was studied by the DTA method for samples having molecular weights of 15500 and 150000. In extended-chain crystallization there was a saturation phenomenon on producing extended-chain crystals. The amount of saturation was dependent on the crystallization temperature. The saturation phenomenon seems to be an important factor for considering the mechanism of growth in extended-chain crystals. The Avrami exponent of extended-chain crystals was almost two. In the case of the folded-chain crystallization, the Avrami exponent was about three, irrespective of pressure. The crystallization rate of folded-chain crystals became more rapid as pressure was increased owing to the depression of the value of excess free energy of the fold surface. The crystallization rate of extended-chain crystals is ako considered to increase with pressure by indirect comparison, and seems to have a maximum crystallization rate near the melting temperature. The estimation of lamellar thickness is discussed for folded-chain crystals produced under high pressure.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
6
Average
Average
Average
bronze