
doi: 10.1271/bbb.64.1761
pmid: 10993172
The marine polyether toxin, 45-hydroxyyessotoxin, was isolated together with yessotoxin from the scallop, Patinopecten yessoensis. The 45-hydroxy group in the side chain was esterified with (S)- and (R)-alpha-methoxyalpha-trifluoromethylphenylacetic acids (MTPA). A detailed analysis of the 2D NMR spectra of the two esters established the R configuration at C45.
45-hydroxyyessotoxin, modified Mosher method, Models, Chemical, Ethers, Cyclic, Mollusca, Oxocins, Animals, Mollusk Venoms, shellfish metabolite, MTPA ester
45-hydroxyyessotoxin, modified Mosher method, Models, Chemical, Ethers, Cyclic, Mollusca, Oxocins, Animals, Mollusk Venoms, shellfish metabolite, MTPA ester
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