An Alternate Synthesis of the Capsaicinoids

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1992 English Publisher:Oxford University Press (OUP)Journal:Bioscience, Biotechnology, and Biochemistry, volume 56, pages 946-948 (issn: 0916-8451, eissn: 1347-6947,

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Authors: KAGA, Harumi; GOTO, Kouhei; FUKUDA, Takashi; ORITO, Kazuhiko;

doi: 10.1271/bbb.56.946

pmid: 27280819

An Alternate Synthesis of the Capsaicinoids

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Abstract

Five capsaicinoids, the pungent ingredients of hot peppers, have been efficiently synthesized by a method involving the Wittig reaction between isobutyl triphenylphosphorane and the appropriate lactols (3), followed by the nitrous acid-induced isomerization of the resultant (Z)-olefins (4) to (E)-olefins (5).

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Hokkaido Bunkyo University
Japan
Hokkaido University
Japan

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