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Chemical and Pharmaceutical Bulletin
Article . 1989 . Peer-reviewed
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Chemical and Pharmaceutical Bulletin
Article . 1989 . Peer-reviewed
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Chemical and Pharmaceutical Bulletin
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Chemical and Pharmaceutical Bulletin
Article . 1990
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https://dx.doi.org/10.1248/cpb...
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Stereochemical studies on the formation of melanin by monophenol monooxygenase.

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1989 English Publisher:Pharmaceutical Society of JapanJournal:Chemical and Pharmaceutical Bulletin, volume 37, pages 3,386-3,389 (issn: 0009-2363, eissn: 1347-5223, Copyright policy )
Authors: KAJIWARA, Masahiro; KURUMAYA, Katsuyuki; KOHNO, Yoshiyuki; TOMITA, Kenichi; CARPENTER, Adrian T.;

doi: 10.1248/cpb.37.3386

pmid: 2517246

Stereochemical studies on the formation of melanin by monophenol monooxygenase.

Abstract

The oxidation of tyrosine by monophenol monooxygenase (tyrosinase: EC 1.10.3.1) to melanin has been studied by a combination of ultraviolet, circular dichroism, and nuclear magnetic resonance techniques. It is demonstrated that the chiral intermediate (dopachrome) is generated stereoselectively in this enzymic reaction.

Keywords

Melanins, stereoselective reaction, Magnetic Resonance Spectroscopy, Chemical Phenomena, dopa, Circular Dichroism, Molecular Conformation, chiral intermediate, dopachrome, tyrosinase, melanin, Chemistry, Spectrophotometry, Ultraviolet, tyrosine, Catechol Oxidase

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    popularity
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    influence
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
5
Average
Average
Average
gold