Localization of Electrons: Blue-shifting Hydrogen Bonds

descriptionPublicationkeyboard_double_arrow_right Article 23 Apr 2005 English Publisher:Oxford University Press (OUP)Journal:Chemistry Letters, volume 34, pages 750-751 (issn: 0366-7022, eissn: 1348-0715,

Copyright policy )

Authors: Satoshi Inagaki; Takahiro Takeuchi;

doi: 10.1246/cl.2005.750

Localization of Electrons: Blue-shifting Hydrogen Bonds

- Summary
- Metrics

Abstract

Abstract A theory of electron localization is developed. Localization is caused by the interaction of an occupied orbital with a vacant orbital. Electrons localize in the occupied orbital rather than delocalize from the occupied orbital to the overlap region. The localization is substantiated by the contraction of the CH bond length of HnCF4−n with the fluorination and successfully applied to the blue-shifting hydrogen bonding of fluoroform with dimethyl ether.

Related Organizations

Gifu University
Japan

Impact byBIP!

	selected citations These citations are derived from selected sources. This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	12
	popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.	Average
	influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	Average
	impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.	Top 10%