Direct Chain Elongation of N-Carbamoylpyroglutamate. An Efficient Synthesis of (−)-Pyrrolidine-2,5-Dicarboxylic Acid

descriptionPublicationkeyboard_double_arrow_right Article 01 Oct 1987 English Publisher:Oxford University Press (OUP)Journal:Chemistry Letters, volume 16, pages 2,091-2,094 (issn: 0366-7022, eissn: 1348-0715,

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Authors: Tomihisa Ohta; Akio Hosoi; Toshihiko Kimura; Shigeo Nozoe;

doi: 10.1246/cl.1987.2091

Direct Chain Elongation of N-Carbamoylpyroglutamate. An Efficient Synthesis of (−)-Pyrrolidine-2,5-Dicarboxylic Acid

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Abstract

Abstract (−)-Pyrrolidine-2,5-dicarboxylic acid, an acidic amino acid component of marine red alga Schizymenia dubyi, has been synthesized with a direct chain elongation reaction of N-carbamoylpyroglutamates at C-5 and a pyrrolidine ring formation.

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Tohoku University
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