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Chemistry Letters
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Chemistry Letters
Article . 1982 . Peer-reviewed
License: OUP Standard Publication Reuse
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https://dx.doi.org/10.1246/cl....
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UNUSUAL REGIOSELECTIVE HYDROSILYLATION OF ETHYNYLMETHYLDICHLOROSILANE WITH DIMETHYLCHLOROSILANE CATALYZED BY TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM(0)

descriptionPublicationkeyboard_double_arrow_right Article 01 Oct 1982 English Publisher:Oxford University Press (OUP)Journal:Chemistry Letters, volume 11, pages 1,663-1,666 (issn: 0366-7022, eissn: 1348-0715, Copyright policy )
Authors: Hideyuki Matsumoto; Yoshikazu Hoshino; Yoichiro Nagai;

doi: 10.1246/cl.1982.1663

UNUSUAL REGIOSELECTIVE HYDROSILYLATION OF ETHYNYLMETHYLDICHLOROSILANE WITH DIMETHYLCHLOROSILANE CATALYZED BY TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM(0)

Abstract

Abstract The hydrosilylation of ethynylmethyldichlorosilane with dimethylchlorosilane catalyzed by tetrakis(triphenylphosphine)platinum(0) was found to show quite an unusual regioselectivity to afford the geminal product, 1-(methyldichlorosilyl)-1-(dimethylchlorosilyl)ethene, almost exclusively.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
13
Average
Top 10%
Average
bronze