ELECTROPHILE INDUCED CYCLIZATION OF FARNESOL

descriptionPublicationkeyboard_double_arrow_right Article 01 Mar 1972 English Publisher:Oxford University Press (OUP)Journal:Chemistry Letters, volume 1, pages 263-266 (issn: 0366-7022, eissn: 1348-0715,

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Authors: Yoshimoto Ohta; Yoshio Hirose;

doi: 10.1246/cl.1972.263

ELECTROPHILE INDUCED CYCLIZATION OF FARNESOL

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Abstract

Abstract The cyclization of farnesol with BF3 etherate in dichloromethane solution afforded α-cedrene, 2-epi-α-cedrene and five new hydrocarbons of muurolane type together with isomeric bisabolenes, α-curcumene and δ-selinene. The structure determination of the new compounds and the formation mechanism of cyclized products are presented.

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