Chemical Interactions between 1,2,4-Triazole-3-thiols and π-Acceptors

descriptionPublicationkeyboard_double_arrow_right Article 01 Sep 1993 English Publisher:Oxford University Press (OUP)Journal:Bulletin of the Chemical Society of Japan, volume 66, pages 2,612-2,616 (issn: 0009-2673, eissn: 1348-0634,

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Authors: Alaa A Hassan; Nasr K Mohamed; Yusria R Ibrahim; Kamal U Sadek; Aboul-Fetouh E Mourad;

doi: 10.1246/bcsj.66.2612

Chemical Interactions between 1,2,4-Triazole-3-thiols and π-Acceptors

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Abstract

Abstract 4-Amino-5-mercapto-5-substituted 4-amino-1,2,4-triazole-3-thiols 1a, b reacted with tetrachloro-, tetrafluoro-p-benzoquinone and 2,3-dichloro-1,4-naphthoquinone as well as 2-(dicyanomethylene)-1,3-indandione via charge-transfer (CT) complex formation giving naphthotriazolothiadiazinone 2a—d, bistriazolobenzobisthiadiazine 3a—d, triazolobenzothiadiazinone 4a, b, bistriazolonaphthobisthiadiazine 5a, b, and indenatriazolothiadiazepine 7a, b derivatives.

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