Crystal Structure of the Gold(III) Complex, Trichloro(dibenzyl sulfide)gold(III)

descriptionPublicationkeyboard_double_arrow_right Article 01 Aug 1991 English Publisher:Oxford University Press (OUP)Journal:Bulletin of the Chemical Society of Japan, volume 64, pages 2,572-2,574 (issn: 0009-2673, eissn: 1348-0634,

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Authors: Kazuhiro Takahashi;

doi: 10.1246/bcsj.64.2572

Crystal Structure of the Gold(III) Complex, Trichloro(dibenzyl sulfide)gold(III)

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Abstract

Abstract The structure of the title complex has been determined. The crystal is orthorhombic, with the space group Pnma, Z=4, a=13.331 (2), b=16.130 (3), and c=7.6949 (9) A. The complex has a square-planar coordination geometry. The Au and the 3C11S donor atoms are located on a crystallographic mirror plane. The length of the Au–Cl bond trans to the Au–S bond is slightly longer than those of the other two Au–Cl bonds.

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