Synthesis of 5,8-Dihydroxy-2-methoxy-1,4-naphthoquinone Derivatives. A Major Naphthoquinone Moiety of Some of Naphthoquinone Antibiotics

descriptionPublicationkeyboard_double_arrow_right Article 01 Aug 1987 English Publisher:Oxford University Press (OUP)Journal:Bulletin of the Chemical Society of Japan, volume 60, pages 2,927-2,930 (issn: 0009-2673, eissn: 1348-0634,

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Authors: Yasuhiro Tanoue; Akira Terada; Toshiyuki Tsuboi; Takayuki Hayashida; Otohiko Tsuge;

doi: 10.1246/bcsj.60.2927

Synthesis of 5,8-Dihydroxy-2-methoxy-1,4-naphthoquinone Derivatives. A Major Naphthoquinone Moiety of Some of Naphthoquinone Antibiotics

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Abstract

Abstract 6-Formyl- and 6-hydroxymethyl-5,8-dihydroxy-2-methoxy-1,4-naphthoquinones were, respectively, prepared from 2-formyl- and 2-hydroxymethyl-1,4,5,6,8-pentamethoxynaphthalenes which were synthesized as key intermediates of the new antibiotics containing 2-methoxynaphthazarin structure.

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Kyushu University
Japan
Kyushu Institute of Technology
Japan

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