Ozonation of Xanthene

descriptionPublicationkeyboard_double_arrow_right Article 01 Feb 1984 English Publisher:Oxford University Press (OUP)Journal:Bulletin of the Chemical Society of Japan, volume 57, pages 603-604 (issn: 0009-2673, eissn: 1348-0634,

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Authors: Masaki Matsui; Yoshihiko Miyamoto; Katsuyoshi Shibata; Yoshimi Takase;

doi: 10.1246/bcsj.57.603

Ozonation of Xanthene

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Abstract

Abstract The ozonation of xanthene was studied using an oxygen stream. Ozone attacks the methylene group of xanthene via a 1,3-dipolar insertion reaction to give the hydrotrioxide intermediate, followed by a loss of singlet oxygen to form xanthydrol. The ozonation of xanthydrol gave singlet oxygen, water and xanthone accompanied by autoxidation.

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Gifu University
Japan

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