Effects of the Oxyethylene Chain Length of Fluorocarbon Surfactants on Demixing of Micelles of Fluorocarbon and Hydrocarbon Surfactants

descriptionPublicationkeyboard_double_arrow_right Article 01 Dec 1983 English Publisher:Oxford University Press (OUP)Journal:Bulletin of the Chemical Society of Japan, volume 56, pages 3,839-3,840 (issn: 0009-2673, eissn: 1348-0634,

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Authors: Noriaki Funasaki; Sakae Hada; Saburo Neya;

doi: 10.1246/bcsj.56.3839

Effects of the Oxyethylene Chain Length of Fluorocarbon Surfactants on Demixing of Micelles of Fluorocarbon and Hydrocarbon Surfactants

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Abstract

Abstract The critical mole fraction of hydrocarbon surfactant decreases with an increase in the oxyethylene unit of either fluorocarbon surfactant or hydrocarbon surfactant. This tendency is explicable in terms of regular solution theory if the depth of water penetration into the micellar interior is assumed to increase with an increase in the oxyethylene unit.

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