Tautomerism of 4-Pyridones

descriptionPublicationkeyboard_double_arrow_right Article 01 Mar 1977 English Publisher:Oxford University Press (OUP)Journal:Bulletin of the Chemical Society of Japan, volume 50, pages 710-712 (issn: 0009-2673, eissn: 1348-0634,

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Authors: Hiromichi Besso; Kimiaki Imafuku; Hisashi Matsumura;

doi: 10.1246/bcsj.50.710

Tautomerism of 4-Pyridones

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Abstract

Abstract The tautomeric constants, Kt, of several 4-pyridones were determined by measurement of pKa values. For 2-substituted 5-methoxy-4-pyridones, the Kt values were correlated to the substituent constants σ, the equation logkt=2.98+2.93σm−6.18σo being obtained.

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Kumamoto University
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