The Direct Chlorination of Anthraquinone Oxime. The Regioselective Chlorination of Anthraquinone

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1977 English Publisher:Oxford University Press (OUP)Journal:Bulletin of the Chemical Society of Japan, volume 50, pages 327-328 (issn: 0009-2673, eissn: 1348-0634,

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Authors: Takehiko Ito; Koichi Sadakata; Yoshiaki Kindaichi; Yasuo Takami;

doi: 10.1246/bcsj.50.327

The Direct Chlorination of Anthraquinone Oxime. The Regioselective Chlorination of Anthraquinone

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Abstract

Abstract The reaction of anthraquinone oxime with chlorine in the presence or absence of a catalyst was investigated. In concentrated sulfuric acid, the direct chlorination of anthraquinone oxime takes place easily at 100 °C. The chlorination occurs selectively in the β-position in the absence of a catalyst and in the α-position in the presence of palladium acetate.

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National Chemical Laboratory
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