The Reaction of Cycloalkanones with Copper(II) Halides. I. The Reaction of Cyclohexanones with Copper(II) Chloride

descriptionPublicationkeyboard_double_arrow_right Article 01 Apr 1975 English Publisher:Oxford University Press (OUP)Journal:Bulletin of the Chemical Society of Japan, volume 48, pages 1,276-1,279 (issn: 0009-2673, eissn: 1348-0634,

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Authors: Kyoko Nishizawa; J Yasuo Satoh;

doi: 10.1246/bcsj.48.1276 , 10.1246/bcsj.48.1875

The Reaction of Cycloalkanones with Copper(II) Halides. I. The Reaction of Cyclohexanones with Copper(II) Chloride

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Abstract

Abstract The reaction of cyclohexanones with copper(II) chloride gave polychlorinated cyclohexanediones directly in fairly good yields. With methylcyclohexanones, in general the type of product depends on the number of methylene groups between the carbonyl group and the methyl-substituted carbon in the starting material. A possible mechanism for the reaction is discussed.

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