Azetidines. II. Some Functional Derivatives of Azetidines

descriptionPublicationkeyboard_double_arrow_right Article 01 Oct 1967 English Publisher:Oxford University Press (OUP)Journal:Bulletin of the Chemical Society of Japan, volume 40, pages 2,398-2,401 (issn: 0009-2673, eissn: 1348-0634,

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Authors: Teng-yueh Chen; Tetutaro Sanjiki; Hiroshi Kato; Masaki Ohta;

doi: 10.1246/bcsj.40.2398

Azetidines. II. Some Functional Derivatives of Azetidines

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Abstract

Abstract The sodium methoxide-catalyzed cyclization of methyl α-tosylamino-γ-chlorobutyrate gave methyl 1-tosylazetidine-2-carboxylate, which was then converted to the corresponding carboxylic acid and carbinol. 1-Acetyl-2,2,4,4-tetramethylazetidine-3-carboxylic acid was prepared by the photolysis of 1-acetyl-4-diazo-2,2,5,5-tetramethylpyrrolidin-3-one. The formation of 1-acetyl-2,2,4,4-tetramethyl-3-azetidinone was confirmed.

Related Organizations

Institute of Science Tokyo
Japan
Laboratory of Organic Chemistry
Switzerland

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