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Vinyl Polymerization. XLVIII. Polymerization of Methylstyrenes and the Effect of Dimethylaniline on their Polymerization

Authors: Minoru Imoto; Kiichi Takemoto; Yuichi Iikubo;

Vinyl Polymerization. XLVIII. Polymerization of Methylstyrenes and the Effect of Dimethylaniline on their Polymerization

Abstract

Abstract 1. Solution polymerizations of styrene, p-methyl-, p-ethyl-, p-tert-butyl-, m-methyl-, 2,4-dimethyl-, 2,5-dimethyl- and 3,4-dimethylstyrene were carried out at 50 and 70°C by ABIN in benzene, and the rates of polymerization and [η]’s of the polymers were determined. For 3,4-dimethylstyrene, the same equation as for styrene was obtained: R 0=k[M] [ABIN]1⁄2 2. Rate constants of initiation of the polymerizations of styrene and p-methylstyrene were determined, according to the FeCl3-method as follows: k i=0.67×10−5 (sec−1) (for p-methylstyrene) k i=0.76×10−5 (sec−1) (for styrene) 3. Polymerizations of styrene and p-methylstyrene were carried out at 70°C by the Bz2O2-DMA system, and the same equation as styrene was derived for p-methylstyrene as follows: R 0=k′[Bz2O2]1⁄2[DMA]1⁄2 4. Polymerizations of styrene, p-methyl-, and dimethylstyrenes were carried out at 50 and 70°C by ABIN-DMA system, and the results for the rate of polymerization and the value of [η] were discussed. A correction was made for the results previously obtained. 5. The effect of DMA on the induction period for the polymerization of p-methylstyrene was studied at 60°C. In the case of polymerization with FeCl3 in DMF, no effect of DMA on the induction period was observed, while in the case of that with p-benzoquinone in benzene, the induction period was decreased with the amount of DMA.

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
2
Average
Average
Average
bronze