Studies on the Cooking Mechanism of Wood. XVI. On the Mechanism of Kraft Cooking

descriptionPublicationkeyboard_double_arrow_right Article 01 Feb 1956 English Publisher:Oxford University Press (OUP)Journal:Bulletin of the Chemical Society of Japan, volume 29, pages 265-270 (issn: 0009-2673, eissn: 1348-0634,

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Authors: Hiroshi Mikawa; Koichiro Sato; Chizuko Takasaki; Kiyo Ebisawa;

doi: 10.1246/bcsj.29.265

Studies on the Cooking Mechanism of Wood. XVI. On the Mechanism of Kraft Cooking

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Abstract

Abstract 1. Hydrogen sulphide cooking of α-guaiacyl propanol (VI) gave bis(1-(4-hydroxy-3-methoxyphenyl)-1-propyl) monosulphide (VIII) and disulphide (VII). 2. Vanillyl monosulphide was decomposed with alkali at 130°. Vanillin, vanillyl alcohol and the secondary products from vanillyl alcohol were identified. 3. The mechanism of the kraft cooking process was discussed and a new mechanism was proposed.

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