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Irreversible Magnetic Properties of Nanocarbon

Authors: Lähderanta E.; Lashkul A.V.; Lisunov K.G.; Zherebtsov D.A.; Galimov D.M.; Titkov A.N.;

Irreversible Magnetic Properties of Nanocarbon

Abstract

Magnetization M(T, B) of powder and glassy samples containing carbon nanoparticles, not intentionally doped and doped with Ag, Au and Co, is investigated at temperatures T between - 3-300 K in magnetic fields B up to 5T. According to atomic force microscopy data, a system of carbon particles has a broad size distribution, given by the average and the maximum radii of -60 nm and - 110 nm, respectively. In low fields of B B(K). The dependence of M(B) saturates above B - 2T at T - 150-300 K and contains a large paramagnetic-like response below - 50-150 K. Hysteresis is observed already at 300 K and is characterized by a power-law temperature decay of the coercive field, B(c)(T). This is described by the exponent n approximately 0.8 and by the low-temperature values of B(c) (0) increasing from -36-53 mT in the undoped sample and those doped with Ag and Au, up to 80 mT in the Co-doped material, yielding the blocking temperatures T(b) approximately 400-580 K. Analysis of the experimental magnetization data above suggests distribution of the magnetization close to the surface of the particles, yielding a thickness of the near-surface layer, h, filled with localized magnetic moments, micro1 - microB, to be close to the average distance, a, between the moments, h approximately a - 1 nm. This is consistent with the origin of magnetism in nanocarbon being presumably due to intrinsic near-surface defects.

Country
Russian Federation
Keywords

Carbon Nano-Particles, Silver, Near-surface layers, 530, Magnetization, Paramagnetism, Carbon, Magnetization data, Atomic force microscopy, Broad size distribution, Blocking temperature, Magnetic moments, Magnetic properties, Localized magnetic moments, Near-surface defects, Nanoparticles, Gold, Field-cooled magnetizations, Glassy carbon

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
2
Average
Average
Average
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