
doi: 10.1166/jnn.2003.183
pmid: 14598444
For quantum-dot cellular automata molecular electronic devices, one of the fundamental tasks is to arrange the molecules on a surface in a controlled manner. In this report, we discuss a molecular lift off technique to form nanopatterns toward the development of molecular circuits. In our molecular lift off technique, we use electron beam lithography to form nano-trenches on a polymethylmethacrylate (PMMA) film on a SiO2 wafer. This wafer is soaked in a Creutz-Taube ion [(NH3)5Ru(pyrazine)Ru(NH3)5](o-toluenesulfonate)5 (CT5) aqueous solution. After residual PMMA removal, atomic force microscopy is used to investigate the resulting surface. Thirty-five nanometer CT5 lines are demonstrated on a SiO2 surface. Compared with other molecular nanopatterning techniques, ours is both economical and capable of high-resolution.
Surface Properties, Molecular Conformation, Electrons, Membranes, Artificial, Microscopy, Atomic Force, Silicon Dioxide, Computers, Molecular, Quantum Dots, Photography, Nanotechnology, Polymethyl Methacrylate, Adsorption, Crystallization
Surface Properties, Molecular Conformation, Electrons, Membranes, Artificial, Microscopy, Atomic Force, Silicon Dioxide, Computers, Molecular, Quantum Dots, Photography, Nanotechnology, Polymethyl Methacrylate, Adsorption, Crystallization
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