The most productive application of graph theory in chemistry is the representation of molecules by the graphs, where vertices and edges of graphs are the atoms and valence bonds between a pair of atoms, respectively. For a vertex w and an edge f = c 1 c 2 of a connected graph G , the minimum number from distances of w with c 1 and c 2 is called the distance between w and f . If for every two distinct edges f 1 , f 2 ∈ E G , there always exists w 1 ∈ W E ⊆ V G such that d f 1 , w 1 ≠ d f 2 , w 1 , then W E is named as an edge metric generator. The minimum number of vertices in W E is known as the edge metric dimension of G . In this paper, we calculate the edge metric dimension of ortho-polyphenyl chain graph O n , meta-polyphenyl chain graph M n , and the linear [n]-tetracene graph T n and also find the edge metric dimension of para-polyphenyl chain graph L n . It has been proved that the edge metric dimension of O n , M n , and T n is bounded, while L n is unbounded.