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Journal of The Electrochemical Society
Article . 2024 . Peer-reviewed
License: IOP Copyright Policies
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A Mg-In Alloy Interphase for Mg Dendrite Suppression

Authors: Brian C. Lee; Kimberly A. See;

A Mg-In Alloy Interphase for Mg Dendrite Suppression

Abstract

Mg metal batteries have attracted much attention as an alternative to Li-ion technology due to the high abundance and volumetric capacity of Mg metal. Further, early reports show that Mg is less prone to dendritic growth compared to Li, thereby improving the safety and long-term reversibility of Mg metal anodes. However, dendritic growth of Mg can be observed in various conditions, causing cell shorting and capacity loss. Herein, we report a chemically-formed Mg-In alloy interphase that suppresses nonuniform Mg growth during electrochemical reduction. Ex-situ X-ray diffraction shows that upon reduction, Mg alloys into the Mg-In interphase with no evidence of Mg deposition on top of the surface during initial cycles. Interestingly, further reduction results in Mg depositing underneath the interphase, which confirms Mg mobility through the interphase. However, the alloying reaction is kinetically limited, leading to significant Mg deposition on top of the interphase at high current densities. Thus, alloys on Mg can affect deposition morphologies, but are limited by the kinetics of Mg conduction through the alloy.

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Keywords

Surfaces, Coatings and Films, Sustainability and the Environment, Materials Chemistry, Electrochemistry, Electronic, Renewable Energy, Optical and Magnetic Materials, Condensed Matter Physics, 540, 530

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
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