Solubility of Calcium in CaCl2-CaO

descriptionPublicationkeyboard_double_arrow_right Article , Other literature type 29 Aug 2008Publisher:The Electrochemical SocietyJournal:ECS Transactions, volume 16, pages 301-308 (issn: 1938-5862, eissn: 1938-6737,

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Authors: Stephen Shaw; Robert Watson;

doi: 10.1149/1.3159334 , 10.1149/ma2008-02/49/2999

Solubility of Calcium in CaCl2-CaO

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Abstract

The solubility of calcium in calcium chloride - calcium oxide is of interest in processes reducing metal oxides in calcium chloride based salt systems. The solubility of calcium in calcium chloride was measured as 2.7mol% at 1073K. This reduced to 0.4mol% at a calcium oxide content of 9.0mol%. Experimental data for the binary components of the calcium - calcium chloride - calcium oxide ternary system has been used to construct a model of the ternary system, against which the results reported here are compared. At high calcium oxide concentrations there is reasonable agreement between model and experiment; at low calcium oxide concentrations the model predicts lower calcium concentrations than found experimentally.

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