The atmosphere of Mars is essentially a pure carbon dioxide atmosphere that contains a small and seasonably varying amount of water vapor. A number of minor constituents which arise from the interactions of solar radiation with water vapor and carbon dioxide include carbon monoxide, atomic oxygen, molecular oxygen, ozone, and atomic hydrogen. At the surface of Mars the atmospheric pressure is less than one hundredth of the pressure at the surface of the earth. Extensive cloud systems appear on Mars. The structure of the lower Martian atmosphere is discussed together with variations in the lower atmosphere and the characteristics of the upper atmosphere. Reactions of photochemistry are considered along with the atmospheric escape and interactions between the atmosphere and the polar caps.