Total synthesis of androstanes

descriptionPublicationkeyboard_double_arrow_right Article 15 Dec 1979 English Publisher:Canadian Science PublishingJournal:Canadian Journal of Chemistry, volume 57, pages 3,356-3,358 (issn: 0008-4042, eissn: 1480-3291,

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Authors: Masatoshi Kakushima; Jagabandhu Das; Gary R. Reid; Peter S. White; Zdenek Valenta;

doi: 10.1139/v79-549

Total synthesis of androstanes

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Abstract

A total synthesis of androstane derivatives is described. The desired configuration at C8 and at C13 is achieved in a ring C forming SnCl4-catalyzed Diels–Alder reaction. The preparation of methyl Z-2-methyl-4-oxo-2-pentenoate and the cyclization of a keto ester to a steroid 15,17-dione are also reported.

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