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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Canadian Journal of ...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Canadian Journal of Chemistry
Article . 1976 . Peer-reviewed
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Pyrochlores. X. Madelung energies of pyrochlores and defect fluorites

Authors: William W. Barker; Peter S. White; Osvald Knop;

Pyrochlores. X. Madelung energies of pyrochlores and defect fluorites

Abstract

Electrostatic (Madelung) lattice energies have been calculated for a wide range of compounds A2B2X6Y with the pyrochlore-type structure. The cases of disorder and partial disorder on the non-metal sites have been examined, as well as the inverse case, where Y is a positive ion. The results of the calculations are compared with those for defect fluorite structure and an attempt is made to relate them to the conditions under which the pyrochlore phase is found. The effect of the site potential in restricting the existence boundaries of the pyrochlore phase is examined, as the potential must have the correct sign relative to the charge occupying the site. Alternative pyrochlore arrangements in which the 8(b) or 32(e) equipoints are occupied have also been explored.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
22
Top 10%
Top 10%
Average
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