Thiohydantoins. VIII. Structure of the reported 5-phenyl-2,4-dithiohydantoin and its benzylation products

descriptionPublicationkeyboard_double_arrow_right Article 01 Apr 1969 English Publisher:Canadian Science PublishingJournal:Canadian Journal of Chemistry, volume 47, pages 1,123-1,128 (issn: 0008-4042, eissn: 1480-3291,

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Authors: J. T. Edward; J. K. Liu;

doi: 10.1139/v69-182

Thiohydantoins. VIII. Structure of the reported 5-phenyl-2,4-dithiohydantoin and its benzylation products

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Abstract

The supposed 5-phenyl-2,4-dithiohydantoin (3) actually exists as its tautomer 5-mercapto-4-phenyl-4-imidazolin-2-thione (12). The reactions of the compound have been clarified by spectral studies of the products; in particular, mono- and dibenzylation have been shown to take place on sulfur and not (as reported) on nitrogen.

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