
doi: 10.1135/cccc19902602
General relations among thermodynamic parameters characterizing chemical equilibria with species I-, I3-, I5-, and I2 in the two-phase water-nitrobenzene extraction system have been derived. Furthermore, these relations have been used for calculating equilibrium constants K1aq(I3-) and K2aq(I5-) corresponding to homogeneous reactions I-(aq) + I2(aq) ⇄ I3-(aq) and I3-(aq) + I2(aq) ⇄ I5-(aq) proceeding in the aqueous phase of the system under study. Finally, stability of polyiodides I3- and I5- in both phases has been discussed.
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